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    • 专利摘要:
    The invention relates to a multilayer security optical component, comprising: - support film (101); a structurable layer (102) deposited on the support film (101); and - a reflective layer of dielectric (103) deposited on the structurable layer (102) discontinuously in the plane of the component, so as to form dielectric areas for drawing patterns (202). It is essentially characterized in that it further comprises: - a set (1040) of at least one layer (1042) comprising fluorescent pigments by UV-B or UV-C excitation, and deposited on said reflective layer of dielectric (103) uniformly or discontinuously in the plane of the optical component.
    公开号:FR3031697A1
    申请号:FR1550354
    申请日:2015-01-16
    公开日:2016-07-22
    发明作者:Antoine Dhome
    申请人:Hologram Industries SAS；
    IPC主号:
    专利说明:

    [0001] OPTICAL SECURITY COMPONENT. FIELD OF THE INVENTION [001] The present invention relates to the field of securing multilayer films. Such multilayer films, also called optical security components, are called security in that they are used for securing identity documents, such as passports and identity cards; for securing fiduciary documents in particular such as bank notes; or for the securing of precious goods; hereinafter 'documents' by brevity. [003] In the case of identity documents or fiduciary documents, a multilayer film is affixed to the document or integrated in the document. In the case of valuable goods, the multilayer film is embedded in a security tag that is affixed to said valuable good or on its packaging. [4] In order to secure the documents, it is known to deposit fluorescent ink 107 under UV-A illumination on an optical component support or possibly integrated in or on the paper support, which is interesting in that such a depot makes it possible to draw patterns that become visible and recognizable by a machine or a human under appropriate illumination. The present invention aims to propose an alternative and secure documents by means of a multilayer film comprising fluorescent pigments by UV-B and / or UV-C excitation, independently of the presence or absence of fluorescent ink. under UV-A lighting. [6] Furthermore, the present invention proposes a new control effect of a transparent security component via a perfect registration between the areas of high optical index, observable under a visible light (spectral band 400 - 800 nm), and areas with fluorescent pigments in the visible under excitation in UVB and / or UVC. SUMMARY OF THE INVENTION [7] More specifically, the invention relates, according to a first of its objects, to a multilayer optical security component, comprising: support film (101); a structurable layer (102) deposited on the support film (101); and a reflective layer of dielectric (103) deposited on the structurable layer (102) discontinuously in the plane of the component, so as to form dielectric areas for drawing patterns (202).
    [0002] It is essentially characterized in that the reflective dielectric layer (103) has a relative transmission in the UV-B or UV-C range of not more than 40%; and characterized in that it further comprises: - an assembly (1040) of at least one layer (1042) comprising fluorescent pigments by UV-B or UV-C excitation, and deposited on said reflective dielectric layer (103); ), uniformly or discontinuously in the plane of the optical component. [008] It is also possible to provide a partially demetallized metal layer (105) deposited on the structurable layer (102) or on the dielectric reflective layer (103). In addition, it is possible to provide: a protective layer (106) deposited selectively on the metal layer (105). It can be provided that the protective layer (106) is screened, so as to present islands whose shape, the spacing between two adjacent islands and the dimensions are predetermined. It can be provided that the reflective layer of dielectric (103) is locally in contact with the structurable layer (102) or in contact with the protective layer (106), so that said optical component presents locally the one of the stacks among: - A successive stack of the support film (101), the structural layer (102) and assembly (1040) of at least one layer (1042) comprising fluorescent pigments by UV-B excitation or UV-C; A successive stacking of the support film (101), the structural layer (102), the dielectric reflective layer (103), and the assembly (1040) of at least one layer (1042) comprising fluorescent pigments by UV-B or UV-C excitation; A successive stacking of the support film (101), the structural layer (102), the dielectric reflective layer (103), the metal layer (105), the protective layer (106), and the assembly ( 1040) of at least one layer (1042) comprising fluorescent pigments by UV-B or UV-C excitation; A successive stacking of the support film (101), the structural layer (102), the metal layer (105), the protective layer (106), the dielectric reflective layer (103), and the assembly ( 1040) of at least one layer (1042) comprising fluorescent pigments by UV-B or UV-C excitation; It can be provided that the structural layer (102) has a set of structures for generating an optically variable image. [0013] It is also possible to provide a detachment layer (109) deposited between the structurable layer (102) and the support film (101) and, by hot activation, to subsequently separate the structurable layer (102) from the support film. (101). It can be provided that the assembly (1040) of at least one layer (1042) comprising fluorescent pigments by UV-B or UV-C excitation is composed of: a layer (1042) of fluorescent ink by UV-B or UV-C excitation, coated with a glue layer (1043); or - a first adhesive layer (1041), a layer (1042) comprising fluorescent pigments by UV-B or UV-C excitation deposited on the first adhesive layer (1041), then a second adhesive layer (1043) deposited on the layer (1042); or - a single layer (1042) comprising fluorescent pigments by UV-B or UV-C excitation also comprising adhesive properties. It can be provided that the dielectric layer (103) is screened, so as to present islands whose shape, the spacing between two adjacent islands and the dimensions are predetermined. The invention also relates to an identity document comprising a multilayer optical security component according to the invention. In particular, said identity document preferably also comprises a set of at least one zone (107) comprising fluorescent pigments by UV-A excitation. According to another of its objects, the invention also relates to a method of manufacturing a security optical component, the method comprising the steps of: - Depositing a structural layer (102) on a support film (101) of plastic or paper, the support film (101) and the structurable layer (102) being adjacent or separated from each other by an assembly of at least one technical layer, - Depositing on the structural layer (102) ) a set (1040) of at least one layer (1042) having fluorescent pigments when subjected to a light source emitting in the UV spectrum, and - uniformly depositing a reflective layer of dielectric (103). It is essentially characterized in that it further comprises steps consisting of, sequentially: - Depositing locally on the structurable layer a layer (108) of varnish or ink soluble in a liquid, in the form of areas in contact with the structurable layer (102) patterning (201) when observed at least in reflection, - Depositing said reflective layer of dielectric (103) on the layer (108) of varnish or ink soluble in a liquid, and at least partially in contact thereof, - Disintegrating the soluble ink (108) by immersing the optical component in said liquid, for locally removing the reflective dielectric layer (103) at each soluble varnish area (108) to replicate said patterns (201) in said disaggregated dielectric reflective layer (103); and depositing said assembly (1040) with at least one layer (1042) comprising fluorescent pigments when they are subjected to a light source emitting in the UV spectrum on the dielectric reflective layer (103) and in contact with it; this. It may further provide a step of: - subjecting the optical component to mechanical stress during its immersion, in particular to ultrasound. It may further provide a step of: - Depositing a set of at least one technical layer between the support film (101) and the structurable layer (102), in particular a detachment layer (104) allowing activation when hot, the support film (101) can subsequently be separated from the structural layer (102). Preferably, the step of depositing said assembly (1040) of at least one layer (1042) comprising fluorescent pigments when they are subjected to a light source emitting in the UV spectrum on the dielectric reflective layer (103) and in contact therewith comprises depositing at least one layer (1042) comprising fluorescent pigments when subjected to a light source emitting in the UV-B or UV-C spectrum. There may be provided a step of depositing said layer (1042) uniformly or selectively on the optical component. Preferably, the step of depositing said assembly (1040) of at least one layer (1042) comprising fluorescent pigments when they are subjected to a light source emitting in the UV spectrum on the dielectric reflective layer (103) and in contact therewith comprises at least one of the steps of: - coating said layer (1042) with a layer of glue; depositing said layer (1042) on a first adhesive layer (1041) and in contact therewith, then coating said layer (1042) with a second adhesive layer (1043); and integrating into said layer (1042), prior to its deposition, adhesive components. In addition, steps may be provided comprising: depositing a metal layer (105) uniformly on the optical component, subsequent to the step of depositing said reflective layer of dielectric (103); - Depositing a protective layer (106) directly in contact with the metal layer (105), selectively in the form of areas patterning patterns when observed at least in reflection; - De-metallizing the metal layer (105) by dissolving the areas of the metal layer (105) unprotected by the protective layer (106), patterning patterns when observed at least in reflection. Furthermore, it is possible to provide steps consisting of, prior to the step of depositing said reflective layer of dielectric (103): depositing a metal layer (105) in a uniform manner on the optical component; - Depositing a protective layer (106) directly in contact with the metal layer (105), selectively in the form of areas patterning patterns when observed at least in reflection; - De-metallizing the metal layer (105) by dissolving the areas of the metal layer (105) unprotected by the protective layer (106), patterning patterns when observed at least in reflection. [0025] Preferably the optical component further comprises a hologram. In this case, the areas of the layer (108) of varnish or ink soluble in a liquid in contact with the structural layer (102) are deposited in register with said hologram, so that the patterns (201) reproduce the contour of said hologram . It is possible to provide zones (202) corresponding to the zones of the optical component for which the dielectric layer (103) has been retained; the method further comprising a step of generating a dithering effect in the zones (202) by depositing the protective layer (106) on the metal layer (105) or deposition of the dielectric layer (103) selectively so as to create islands whose shape, the spacing between two adjacent islands and the dimensions are predetermined. Other features and advantages of the present invention will appear more clearly on reading the following description given by way of illustrative and non-limiting example and with reference to the accompanying figures.
    [0003] DESCRIPTION OF THE DRAWINGS FIG. 1 illustrates a cross section of a multilayer film according to the prior art; FIGS. 2A to 2D illustrate, in cross-section, a first embodiment of an optical component according to the invention, FIGS. 3A to 3G illustrate, in cross-section, a second embodiment of an optical component according to the invention, FIGS. 4A to 4F sequentially illustrate in cross-section a third embodiment of an optical component according to the invention; FIG. 5A illustrates a reflection view of an optical component according to the invention illuminated a source of visible light; FIG. 5B illustrates a reflection view of the optical component of FIG. 5A illuminated by a UV-A light source; FIG. 50 illustrates a reflection view of the optical component of FIG. 5A illuminated by a UV-C light source; FIG. 6 illustrates the transmission variation of a ZnS layer as a function of its thickness, and FIGS. 7A and 7B illustrate two stages of realization of a mode of real isation of an optical component according to the invention, comprising a hologram. DETAILED DESCRIPTION For the sake of simplicity, here is meant "optical component" and "multilayer film"; "Ink" and "varnish"; "Film" and "layer".  Similarly, an optical component is described here as being plane.  Depending on its constituent materials, it may nevertheless have some flexibility, particularly when the optical component is in the form of self-adhesive label.  By UV-A is meant the spectrum 315-400 nm, UV-B the spectrum 280-315 nm and UV-C the spectrum 100-280 nm.  A multilayer security film is intended to be observed at least in reflection.  It comprises a front face and a rear face (Figure 1).  By convention, the term "front face" defines the face by which the optical component can be illuminated in reflection and "back side" that which is intended to be in contact with a support called "destination", for example paper, polycarbonate, pvc, or plastic, and for example by an adhesive.  The destination medium can also have a transparency or opacity less than that of the optical component.  Moreover, the relative position of certain layers can affect the optical effects of said component.  During the manufacture of the film, at least some layers are deposited in a predetermined order in order to give the optical security component its optical properties, as described later.  Within the meaning of the present invention, by convention, it is considered that a cross section of the optical component is oriented so that the bottom of the optical component corresponds to the front face, that is to say the structural layer 102 or the support film 101, and that the top of the optical component corresponds to the rear face, that is to say the layer 104 or the assembly 1040, described later.  Thus, if a given layer A is deposited on another given layer B, the term "deposited on" means that the layer A is located above the layer B in cross-section, without necessarily being in contact with it.  In terms of manufacturing process, this means, unless otherwise specified, that layer A is subsequently deposited at layer B.  Prior art [0034] Figure 1 illustrates a cross section of a conventional multilayer film, intended to be affixed to a document 300 comprising a destination medium 301.  Its manufacturing process is as follows.  On a support film 101 of plastic, essentially allowing the manufacture of the optical component and typically polyethylene terephthalate (PET) or equivalent, a structural layer 102 is deposited.  The support film 101 serves essentially for the manufacture of the optical component.  The layer 102 is said to be "structurable" in that it is capable of locally comprising structures, that is to say reliefs and recesses, the dimensions of which (in particular the height) are typically between the nanometer and the micrometer, and which influence the reflection, diffraction or diffusion of an incident electromagnetic wave.  The layer 102 is said to be "structured" when it comprises such structures.  For example, the structuring layer may be structured by hot stamping a thermoformable varnish or by cold molding and UV curing an ad hoc varnish (casting varnish) to give the layer 102.  Furthermore, the support film 101 and the structural layer 102 may be adjacent or separated from each other by a set of at least one so-called "technical layer" layer such as for example a so-called "detachment" layer. 109 allowing during hot activation to subsequently separate the support film 101 from the structural layer 102.  During the manufacture of the optical component, a zinc sulphide (ZnS) layer 103 of thickness between 10 and 500 nm is deposited by thermal evaporation under vacuum or by any other appropriate mode (electron beam, etc.). . . . ).  This layer ZnS 103 uniformly covers the entire surface of the component, that is to say the entire surface of the structural layer 102.  Certain multilayer films further comprise the locally localized deposition of a fluorescent ink 107 by UV-A excitation.  Alternatively, the zones of a UV-A excitation fluorescent ink 107 may be deposited not on the multilayer film but on the destination medium 301, as illustrated in FIG.  Fluorescent ink zones typically allow to draw an observable pattern in reflection.  Then, a technical layer 104 is coated on the entire ZnS layer 103.  When the component comprises fluorescent ink zones 107, these are also covered by the technical layer 104.  The technical layer 104 may be an adhesive layer, comprising an adhesive material; and / or a protective layer, comprising for example a varnish.  Invention [0041] There is proposed here a new way quite clever to achieve similar patterns.  For this purpose, it is expected that the absolute value of the optical index variation between the structural layer 102 and the reflective layer of dielectric 103 is greater than or equal to 0.5.  In addition, the reflective layer of dielectric 103, advantageously with high optical index, has a relative transmission in the UV-B and / or UV-C range of not more than 40%, is discontinuous in the plane of the component, so to realize dielectric zones for drawing patterns.  This reflective layer of dielectric 103 is then coated by an assembly 1040 of at least one layer 1042 comprising fluorescent pigments by UV excitation, and in particular UV-B or UV-C, as described below.  The term "fluorescent" is used concisely.  For the purposes of the present invention, the term "fluorescent" must be understood as "luminescent photo", that is to say also encompassing phosphorescence.  In all the embodiments below, it is expected that a structural layer 102 is deposited on a support film 101, in this case plastic.  The structurable layer 102 and the support film 101 may be directly in contact with each other, as illustrated.  It is also possible to provide a set of at least one technical layer between the structurable layer 102 and the support film 101.  For example, a so-called "detachment" layer 109 which by hot activation subsequently separates the structurable layer 102 from the support film 101 is deposited between the structurable layer 102 and the support film 101, as illustrated in FIG.  First Embodiment [0046] A first embodiment is illustrated in FIGS. 2A to 2D.  As illustrated in FIG. 2A, selective deposition is provided, in this case by printing, in particular by gravure printing, of a partial layer of soluble varnish 108 (for example an ink based on polyvinyl alcohol) on the layer. structurable 102, preferably directly in contact therewith.  Selective deposition in the form of zones of soluble varnish 108 makes it possible to draw patterns 201 when they are observed at least in reflection.  It is then expected to cover the component, in this case the structured layer 102 and soluble varnish areas 108 by a reflective layer of dielectric 103 (typically ZnS or TiO 2), as shown in Figure 2B.  Once the reflective layer of dielectric 103 deposited by any known means, it is expected to disintegrate the layer 108 for example by immersion of the optical component in a suitable bath, that is to say a bath comprising a solution that disintegrates the soluble varnish 108 in contact therewith.  The destruction of the layer 108 has the effect of locally removing the reflective layer of dielectric 103 at the locations of each zone of soluble varnish 108, as shown in Figure 2C.  Such techniques are known, for example from US 6896938.  It can further be provided to subject the optical component to mechanical stress during its immersion, for example by a step of subjecting the optical component to ultrasound, which facilitates the disintegration of the soluble ink 108.  Thus, the pattern 201 drawn by the disaggregated areas of the dielectric reflective layer 103 reproduces the pattern 201 drawn by the varnish areas 108 before their dissolution, 35 why these two patterns here bear the same reference numeral.  As explained later, the pattern 201 is fluorescently observable when illuminated by a light source emitting in the UV spectrum, but less visible when illuminated by a light source emitting in the visible spectrum.  It is then expected to coat the optical component of a set 1040 of at least one layer 1042 comprising fluorescent pigments by UV excitation, hereinafter "the" layer 1040 concisely, see Figure 2D.  By "fluorescent pigments by UV excitation" or "UV fluorescence ink", it is meant that the pigments (or the ink comprising such pigments) are fluorescent when subjected to a light source emitting in the field of length of UV wave, in particular UV-B or UV-C.  The assembly 1040 can be made by at least one of the following variants: In a first variant, the assembly 1040 is composed of a layer 1042 of fluorescent ink by UV excitation, coated with a layer of glue 1043.  In a second variant, the assembly 1040 is composed of a first adhesive layer 1041, a layer 1042 of fluorescent ink by UV excitation, and a second adhesive layer 1043.  In a third variant, the assembly 1040 is composed of a single layer 1042 of fluorescent ink by UV excitation also comprising adhesive properties.  The layer 1042 of UV fluorescence ink may be uniformly applied to the optical component, in which case the pattern 201 appearing under UV light observation corresponds to the pattern constituted by the disaggregated areas of the dielectric reflective layer 103, whose pattern advantageously corresponds to the pattern of soluble dissolvable 108 dissolved (Figure 2D).  The UV fluorescence ink layer 1042 may be selectively applied to the optical component, thereby creating UV fluorescence ink areas for patterning when viewed in UV light reflection.  In this case, a combination of the pattern drawn by the UV fluorescence ink layer 1042 and the pattern 201 drawn by the disaggregated zones of the dielectric reflective layer 103, in which the fluorescence is observable only in areas printed with UV fluorescence ink which are not covered by reflective dielectric reflective layer areas 103.  Thus, the observation of the optical component in UV light reflection makes it possible to generate an observable image on three levels: an absence of UV fluorescence ink, a UV fluorescence ink filtered by the dielectric, and a UV fluorescence ink. .  The structural layer 102 may be directly in contact with reflective dielectric layer areas 103, directly in contact with UV fluorescence ink zones 1042, or in contact with a first adhesive layer 1041.  The lower face (reflection side) of the assembly 1040 of at least one layer 1042 comprising fluorescent pigments by UV excitation is in direct contact with the structurable layer 102 or in direct contact with a reflective layer area of dielectric 103.  In this embodiment, the optical component can therefore comprise locally one of the following stacks: - A successive stack of layers 101, 102, 1040; or - a successive stack of the layers 101, 102, 103, 1040.  Second Embodiment [0061] A second embodiment is illustrated in FIGS. 3A to 3G.  In the second embodiment, it is provided, as in the first embodiment illustrated in FIG. 2A, a selective deposition of a partial layer of soluble varnish 108 (for example an ink based on polyvinyl alcohol) on the structured layer 102, preferably directly in contact with it, and in this case by printing, in particular by gravure printing.  Selective deposition in the form of soluble varnish zones 108 makes it possible to draw patterns when they are observed at least in reflection.  It is then expected to cover the component, in this case the structured layer 102 and soluble varnish areas 108 by a reflective layer of dielectric 103 (typically ZnS or TiO 2), as shown in Figure 2B.  Once the reflective layer of dielectric 103 deposited by any known means, it is expected to immerse the optical component to disintegrate the soluble ink 108 which, by its destruction, locally removes the reflective layer of dielectric 103 to the right of each zone of soluble varnish 108, as illustrated in FIG.  Such techniques are known, for example from US 6896938.  It can further be provided to subject the optical component to mechanical stress during its immersion, for example by a step of subjecting the optical component to ultrasound, which facilitates the disintegration of the soluble ink 108.  Thus, the pattern drawn by the zones of the reflective dielectric layer 103 disintegrated reproduces the pattern drawn by the areas of varnish 108 before their dissolution.  The embodiments illustrated in FIGS. 2A, 2B and 20 are therefore identical to the embodiments illustrated in FIGS. 3A, 3B and 30 respectively.  In the second embodiment, provision is then made for the deposition of a metal layer 105, uniformly applied to the optical component, which has the advantage of having visually different optical characteristics such as, for example, opacity, reflectivity, diffraction gain, and / or allow plasmonic effects that require the presence of a metal layer.  Directly in contact with the metal layer 105 is then provided for the selective deposition of a protective layer 106, in this case a varnish, as shown in Figure 3E.  The selective deposition by protective layer zones 106 makes it possible to draw patterns (not shown).  It is then expected to de-metallize the metal layer 105, in this case by immersion of the optical component in a sodium hydroxide solution.  The areas of the metal layer 105 unprotected by the protective layer 106 are then dissolved, as shown in FIG 3F, which also creates a pattern (not shown) by de-metallization of the metal layer 105.  Then, as in the first embodiment, it is expected to coat the optical component of a set of at least one layer comprising fluorescent pigments in the visible by UV excitation 1040, hereinafter "the" layer 1040 by concision.  The assembly 1040 can be achieved by at least one of the following variants.  In a first variant, the assembly 1040 is composed of a layer 1042 UV fluorescence ink in the visible by UV excitation, coated with a layer of glue.  In a second variant, the assembly 1040 is composed of a first adhesive layer 1041, a layer 1042 of UV fluorescence ink in the visible light by UV excitation (for example a protective coating layer), and then a second adhesive layer 1043.  In a third variant, the assembly 1040 is composed of a single layer 1042 UV fluorescence ink in the visible UV excitation also comprising adhesive properties (see Figure 3G).  In this embodiment, the assembly 1040 is applied uniformly to the optical component, in which case the pattern 204 appearing under observation under UV-B or UV-C light corresponds to the pattern formed by the zones of the layer. dielectric reflective material 103, the pattern of which corresponds advantageously to the pattern of dissolvable varnish 108, with the exception of the metallized zones (FIG. 3G).  The structural layer 102 may be directly in contact with reflective dielectric layer regions 103, directly in contact with the assembly 1040 comprising UV fluorescence ink zones, or in contact with the zones of the metal layer 105 protected by the protective layer 106.  The areas of the metal layer 105 protected by the protective layer 106 are in direct contact.  They can be either in contact with the structural layer 102, or stacked on reflective layer regions of dielectric 103.  The upper face of the structural layer 102 is in contact with reflective dielectric layer areas 103, of the assembly 1040 of at least one layer comprising fluorescent pigments the whole 1040 by UV excitation, or in contact with zones of the metal layer 105.  The upper face of the zones of the metal layer 105 is in direct contact with the protective layer 106.  The lower face (reflection side) of the zones of the metal layer 105 is in contact with the structurable layer 102 or in contact with reflective layer areas of dielectric 103.  In this embodiment, the optical component can therefore locally include one of the following stacks: - A successive stack of layers 101, 102, 1040; - A successive stack of the layers 101, 102, 103, 1040; or - a successive stack of layers 101, 102, 103, 105, 106, 1040.  The second embodiment advantageously allows, with respect to the first embodiment, to locally add a stack of zones of the metal layer 105 in direct contact with the protective layer 106, which makes it possible to draw additional patterns. , visible in reflection, thanks to the metal layer 105 partially de-metallized.  Third Embodiment [0083] A third embodiment is illustrated in FIGS. 4A-4F.  It is expected the deposition of a metal layer 105, applied uniformly on the optical component, in this case directly in contact with the structurable layer 102, as shown in Figure 4A.  Directly in contact with the metal layer 105 is then provided selectively depositing a protective layer 106, in this case a varnish, as shown in Figure 4B.  The selective deposition by protective layer zones 106 makes it possible to draw patterns.  It is then expected to de-metallize the metal layer 105, for example by immersion of the optical component in a sodium hydroxide solution.  De-metallization, or partial metallization, is known for example from US5145212.  The areas of the metal layer 105 unprotected by the protective layer 106 are then dissolved, as shown in FIG 4B.  Selective deposition is provided, in this case by printing, in particular by gravure printing, of a partial layer of soluble varnish 108 (for example an ink based on polyvinyl alcohol) in contact with the structurable layer 102 or in contact with at least one protective layer area 106, see Figure 40.  Selective deposition in the form of soluble varnish zones 108 makes it possible to draw patterns when they are observed at least in reflection.  It is then expected to cover the component, in this case the structured layer 102, the areas of soluble varnish 108, and the areas of the metal layer 105 protected by the areas of the protective layer 106, by a reflective layer dielectric 103 (typically ZnS or titanium dioxide (TiO2)), as illustrated in FIG. 4D.  Once the reflective layer of dielectric 103 deposited by any known means, it is expected to immerse the optical component to disintegrate the soluble ink 108 which, by its destruction, locally removes the reflective layer of dielectric 103 at the locations of each zone of soluble varnish 108, as illustrated in FIG. 4E.  Thus, the pattern drawn by the zones of the reflective dielectric layer 103 disintegrated reproduces the pattern drawn by the varnish areas 108 before their dissolution (ignoring the metallized areas).  It may further be provided to subject the optical component to mechanical stress during its immersion, for example by a step of subjecting the optical component to ultrasound, which facilitates the disintegration of the soluble ink 108.  Then, as in the first embodiment, it is expected to coat the optical component of a set of at least one layer comprising fluorescent pigments in the visible by UV excitation, hereinafter "the" layer 1040. by brevity.  The assembly 1040 can be achieved by at least one of the following variants.  In a first variant, the assembly 1040 is composed of a layer 1042 UV fluorescence ink in the visible by UV excitation, coated with a glue layer 1043.  In a second variant, the assembly 1040 is composed of a first adhesive layer 1041, a layer 1042 of UV fluorescence ink in the visible light by UV excitation (for example a protective coating layer), and then a second adhesive layer 1043.  In a third variant, the assembly 1040 is composed of a single layer 1042 UV fluorescence ink in the visible UV excitation also comprising adhesive properties (see Figure 4F).  In this embodiment, the assembly 1040 is uniformly applied to the optical component, in which case the pattern appearing under observation under UV light corresponds to the pattern constituted by the zones of the disaggregated dielectric reflective layer 103, of which the pattern advantageously corresponds to the dissolvable dissolvable pattern 108 (FIG. 4F), with the exception of the metallized zones.  The structural layer 102 may be directly in contact with reflective dielectric layer areas 103, directly in contact with the assembly 1040 comprising UV fluorescence ink zones, or in contact with the zones of the metal layer 105 protected by the protective layer 106.  The upper face of the zones of the metal layer 105 is in direct contact with the protective layer 106.  The lower face (reflection side) of the zones of the metal layer 105 is in contact with the structurable layer 102.  The upper face of the zones of the dielectric reflective layer 103 is in direct contact with the assembly 1040 comprising UV fluorescence ink zones.  The lower face (reflection side) of the zones of the dielectric reflective layer 103 is in direct contact with the structurable layer 102, or in direct contact with the protective layer 106.  The upper face (transmission side) of the protective layer 106 may be in contact with at least one of the zones of the reflective layer of dielectric 103 or in direct contact with the assembly 1040 comprising ink zones to UV fluorescence.  In this embodiment, the optical component can therefore comprise locally one of the following stacks: - A successive stack of the layers 101, 102, 1040; - A successive stack of the layers 101, 102, 103, 1040; or - a successive stack of the layers 101, 102, 105, 106, 103, 1040; Application to a Secure Document [00107] Whatever its embodiment, an optical component according to the invention is advantageously integrated into any secure document, for example an identity document, a passport, etc.  or a fiduciary document, for example a bank note.  It can also be in the form of a label to be glued to a product or valuable.  The secure documents 200 have a destination medium in the form of paper or plastic which incorporates patterns 203 visible only under illumination by a light source emitting in the UV-A (FIG. 5B).  The dielectric used for the reflective layer 103 is preferably ZnS, and the ink used for the layer 1042 is a UV-fluorescence ink in the visible range by UV-C or UV-B excitation because the ZnS is a absorption filter UV-B and UV-C, as shown in Figure 6 which is an experiment curve performed by the applicant.  FIG. 6 illustrates the relative transmission variation of the fluorescence emitted by a layer 1042 whose thickness and pigment concentration are normalized, through a layer of ZnS, as a function of the thickness of the ZnS layer. , and for three values of the wavelength: a wavelength λ = 250 nm (UV-C), a wavelength λ = 300 nm (UV-B) and a wavelength λ = 350 nm (UV-A).  Such pigments are known for example from documents WO2014048702 and WO2009005733.  The decrease of the transmission as a function of the thickness clearly illustrates the filter effect exerted by the ZnS layer.  The fluorescence emitted by the pigments under UV-C is lower than that of the pigments under UV-B, itself lower than that of pigments under UV-A.  It is estimated empirically that below a relative transmission equal to 40%, the fluorescence is no longer observable.  Thus, for layer thicknesses of between 20 nm and 140 nm, said layer 103 is indeed a spectral filter blocking the fluorescence of the pigments of the layer 1042 under UV-B or UV-C whereas the fluorescence of the possible [00106] The third embodiment advantageously allows, with respect to the second embodiment, to locally interchange the position of the zones of the dielectric reflective layer 103 relative to the stack of zones of the metal layer 105 in direct contact with the layer. protection 106, which makes it possible not to subject the dielectric deposit in the de-metallization step of the metal which can cause deterioration of the layer.  ink pigments 107 remain observable.  Assuming that a destination medium comprises a fluorescent pigment ink 107 under UV-A illumination and that the optical component according to the invention is locally superimposed with at least one partial layer 107, the presence of dielectric 103 according to the invention does not impede the reading of the pattern drawn by the ink zones 107 under UV-A illumination.  the optical component according to the invention is therefore compatible with the presence of such inks in a destination medium or in said optical component.  Under UV-C or UV-B illumination, the ZnS screens the fluorescence of the ink of the layer 1042, so only the patterns 201 of any of the preceding embodiments give rise to visible fluorescence. in the form of fluorescent patterns 204.  The zones or patterns 201 correspond to the zones of the optical component for which the dielectric 103 has been removed locally and the zones or patterns 202 correspond to the zones of the optical component for which the dielectric 103 has been retained.  Thus, since the manufacturer of the proposed optical component has no control over the position of the visible patterns 203 under UV-A lighting, the creation of a visible pattern UV-C and / or UV-B advantageously allows not to interfere with the reading of said patterns 203 under UV-A illumination, and vice versa, that the patterns 203 visible under UV-A light do not disturb the reading of the visible patterns 201 under UV-C and / or UV-B illumination.  Hologram It can be provided that the multilayer film further comprises a surface having an optically variable image, also called hologram or holographic image 205, that is to say a set of microstructured zones of the structural layer 102 designed to produce an optically variable visual effect also known as DOVID (Diffractive Optical Variable Image Device) which in itself increases the security of the optical component.  The DOVID commonly called "hologram" (not shown), observable in visible light, is generated thanks to a stamping of the structural layer 102 and is visible on the finished product only in the zones comprising a reflective layer (metal 105 or high optical index 103), that is to say in one of the zones 202.  In the areas of the optical component where the layer 102 is in direct contact with the assembly 1040, the network is said to be "plugged" and the holographic image is no longer observable.  The surface of the hologram and the pattern 201 visible in UV can be complementary (except if metal presence) from one another.  It is advantageous that the areas of soluble varnish 108 are deposited in register with the hologram.  For this purpose, it can be provided that the soluble varnish 108 is slightly colored to facilitate positioning.  Thus, thanks to the invention, it is possible to create a visible pattern UV-C and / or UV-B identical in its contours and in its position to the hologram, by a soluble ink deposit 108 in registration with the hologram.  Without this solution, the falsification of a secure document comprising a hologram and an identical pattern visible in UV would typically consist of superimposing a layer comprising the UV fluorescence ink pattern on the holographic layer of the optical component.  But such a superposition is never perfect if only by the mechanical tolerances involved.  On the contrary, the invention allows a perfect trimming of the hologram UV-C and / or UV-B by the generation of the hologram and the pattern 201 visible in UV during the same manufacturing process, which increases the security level of the optical component.  In this case, it is preferably provided that the lateral extension D2 of the hologram 205 is smaller than the lateral extension D1 of the structured zone of the structural layer 102 capable of carrying the said hologram.  For this purpose, it is possible to deposit the ink 108 partially on the structured zone of the layer 102 (FIG. 7A), which gives, after deposition of the dielectric layer 103 and disintegration of the ink 108, a hologram 205 whose outline is fluorescent (FIG. 7B) when it is illuminated by a UV-B or UV-C source, by the zones 201.  For the verification of the authenticity of the document, steps may be provided to illuminate the document in visible light and to record the position of the hologram in a memory, to illuminate the document in UV-C and / or UV-light. B and save the position of the pattern 201 in a memory, then compare the two images, in particular compare their position.  Screening In the second and third embodiments, provision may furthermore be made for the protective layer 106 to be deposited on the metal layer 105 selectively so as to create islands whose shape, the spacing between two adjacent islands and the dimensions are predetermined, which typically generates a dithering effect on the areas 202 comprising dielectric.  It can also be provided that the dielectric layer 103 is screened, that is to say selectively deposited so as to create islands whose shape, the spacing between two adjacent islands and the dimensions are predetermined, This makes it possible to create very small insignificant areas in visible light which form a significant pattern under UV-B or UV-C illumination.  Transparency [0128] According to the invention, the support layer 101, when it is not detachable from the optical component, the structurable layer 102, the dielectric reflective layer 103 and the assembly 1040 of at least one layer comprising pigments UV-excited fluorescents are preferably at least partially transparent in the visible, so that data carried by the document 300 can be recognized optically when the optical component is affixed to the document and that it is illuminated in the visible range.  Nomenclature 100 Optical component 101 Support layer 102 Structurable layer 103 Reflective dielectric layer (ZnS, TiO 2. . . ) 104 Technical layer 105 Metal layer 106 Metallic layer protection layer 107 UV-A excitation fluorescent ink partial layer 108 Liquid-soluble varnish or ink layer 200 Secure document 201 Design drawn by the zones of the reflective dielectric layer disaggregated, or pattern drawn by the zones of varnish 108 before their dissolution, in visible light, seen in reflection 202 Pattern corresponding to the areas of the optical component for which the dielectric 103 has been preserved, seen in reflection 203 Reason visible only under illumination by a light source emitting in the UV-A 204 Motif 201 fluorescent, illuminated in UV-C light 205 DOVID: Structured area of the structural layer in contact with the reflective dielectric layer 300 Document 301 Destination medium 1040 Set of at least one layer comprising fluorescent pigments by UV-B or UV-C excitation 1041 First adhesive layer 1042 Neck having fluorescent pigments by UV-B or UV-C excitation 1043 Second adhesive layer 30
    权利要求:
    Claims (10)
    [0001]
    REVENDICATIONS1. Multilayer optical security component, comprising: - support film (101); a structurable layer (102) deposited on the support film (101); and a reflective layer of dielectric (103) deposited on the structurable layer (102) discontinuously in the plane of the component, so as to provide dielectric areas for drawing patterns (202); characterized in that the reflective dielectric layer (103) has a relative transmission in the UV-B or UV-C range of not more than 40%; and characterized in that it further comprises: an assembly (1040) of at least one layer (1042) comprising fluorescent pigments by UV-B or UV-C excitation, and deposited on said reflective dielectric layer (103), uniformly or discontinuously in the plane of the optical component. 15
    [0002]
    The multilayer optical security component of claim 1, further comprising a partially demetallized metal layer (105) deposited on the structurable layer (102) or on the reflective dielectric layer (103). 20
    [0003]
    A multilayer optical security component according to any one of the preceding claims, further comprising: - a protective layer (106) selectively deposited on the metal layer (105).
    [0004]
    4. The multilayer security optical component according to claim 3, wherein the protective layer (106) is screened, so as to present islands whose shape, the spacing between two adjacent islands and the dimensions are predetermined.
    [0005]
    A multilayer security optical component according to any one of claims 3 or 4, wherein the reflective dielectric layer (103) is locally in contact with the structurable layer (102) or in contact with the protective layer (106). ), so that said optical component has locally one of the stacks among: - A successive stack of the support film (101), the structural layer (102) and set (1040) of at least one layer ( 1042) comprising fluorescent pigments by UV-B or UV-C excitation; - A successive stack of the support film (101), the structural layer (102), the reflective layer of dielectric (103), and set (1040) of at least one layer (1042) comprising fluorescent pigments by UV-B or UV-C excitation; - A successive stacking of the support film (101), the structural layer (102), the dielectric reflective layer (103), the metal layer (105), the protective layer (106), and assembly (1040) of at least one layer (1042) comprising fluorescent pigments by UV-B or UV-C excitation; A successive stacking of the support film (101), the structural layer (102), the metal layer (105), the protective layer (106), the dielectric reflective layer (103), and the assembly ( 1040) of at least one layer (1042) comprising fluorescent pigments by UV-B or UV-C excitation;
    [0006]
    A multilayer security optical component according to any one of the preceding claims, wherein the structural layer (102) has a set of structures for generating an optically variable image.
    [0007]
    A multilayer security optical component according to any one of the preceding claims, further comprising a detachment layer (109) deposited between the stretchable layer (102) and the support film (101), and allowing by hot activation of subsequently separating the structurable layer (102) from the support film (101).
    [0008]
    8. multilayer security optical component according to any one of the preceding claims, wherein set (1040) of at least one layer (1042) comprising fluorescent pigments by UV-B or UV-C excitation is composed of: - d ' a UV-B or UV-C excitation fluorescent ink layer (1042) coated with a glue layer (1043); or - a first adhesive layer (1041), a layer (1042) comprising fluorescent pigments by UV-B or UV-C excitation deposited on the first adhesive layer (1041), then a second adhesive layer (1043) deposited on the layer (1042); or - a single layer (1042) comprising fluorescent pigments by UV-B or UV-C excitation also comprising adhesive properties.
    [0009]
    A multilayer security optical component according to any one of the preceding claims, wherein the dielectric layer (103) is screened, so as to present islands whose shape, the spacing between two adjacent islands and the dimensions are predetermined. .
    [0010]
    An identity document comprising a multilayer security optical component according to any one of the preceding claims, said identity document preferably further comprising a set of at least one zone (107) comprising fluorescent pigments by UV excitation. -AT.
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    同族专利:
    公开号 | 公开日
    PH12017501286A1|2018-01-15|
    MX2017009316A|2017-12-11|
    CN107405942B|2018-08-03|
    CN107405942A|2017-11-28|
    EP3245074B1|2020-05-20|
    EP3245074A1|2017-11-22|
    US9962987B2|2018-05-08|
    US20180029402A1|2018-02-01|
    BR112017015096A2|2018-04-17|
    FR3031697B1|2020-12-18|
    MX361360B|2018-12-04|
    WO2016113517A1|2016-07-21|
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    法律状态:
    2015-12-22| PLFP| Fee payment|Year of fee payment: 2 |
    2016-07-22| PLSC| Search report ready|Effective date: 20160722 |
    2016-12-21| PLFP| Fee payment|Year of fee payment: 3 |
    2017-01-20| CD| Change of name or company name|Owner name: SURYS, FR Effective date: 20161220 |
    2017-12-21| PLFP| Fee payment|Year of fee payment: 4 |
    2019-12-19| PLFP| Fee payment|Year of fee payment: 6 |
    2020-12-17| PLFP| Fee payment|Year of fee payment: 7 |
    优先权:
    申请号 | 申请日 | 专利标题
    FR1550354A|FR3031697B1|2015-01-16|2015-01-16|OPTICAL SECURITY COMPONENT.|FR1550354A| FR3031697B1|2015-01-16|2015-01-16|OPTICAL SECURITY COMPONENT.|
    PCT/FR2016/050083| WO2016113517A1|2015-01-16|2016-01-15|Optical security component|
    EP16705562.3A| EP3245074B1|2015-01-16|2016-01-15|Identification document|
    US15/543,647| US9962987B2|2015-01-16|2016-01-15|Optical security component|
    BR112017015096-4A| BR112017015096A2|2015-01-16|2016-01-15|identity card|
    CN201680010266.1A| CN107405942B|2015-01-16|2016-01-15|Optical security component|
    MX2017009316A| MX361360B|2015-01-16|2016-01-15|Optical security component.|
    PH12017501286A| PH12017501286A1|2015-01-16|2017-07-14|Optical security component|
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